Why is relative no. of atoms of moles = percentage of that element in compound/atomic mass?? How??
Like given in pic!

Why is relative no. of atoms of moles = percentage of that element in compound/atomic mass?? How?? Like given in pic! Example- 40 Calculate the empirical formula of a compound that contains 26.6% potassium, 35.4% chromium and 38.1% oxygen [Given Sol. Element Potassium Chromium Oxygen Relative no. Of atoms • -0.68 39.1 = 0.68 52 38.1 = 2.38 16 Percentage 26.6 35.4 38.1 Simplest ratio 0.68 0.68 0.68 0.68 2.38 = 3.5 0.68 Atomic mass 39.1 52.0 16.0 Simplest whole no. ratio IX2-2 1 x 2-2 3.50=7 Therefore, empirical formula is K2Cr20,.

Dear Student,

For finding empirical formula we need to find  relative no. of atoms which can be obtained by percentage of that element in compound/atomic mass. A example i want to show you like your example 


Empirical formula can be calculated from the  % composition

For ex., 
A compound is found to contain 65.44% C, 5.49% H and 29.07% O .What is its empirical formula.
Element % At mass % / at mass Simple ratio Whole no ratio
C 65.44 12 65.44 / 12 = 5.45  5.45 / 1.82 = 2.99  3
H 5.49 1 5.49 / 1 = 5.49 5.49 / 1.82 = 3.02  3 
O 29.07 16 29.07 / 16 = 1.82 1.82 / 1.82 = 1  1


Thus the empirical formula is C3H3O
 

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It is the only method to fing empirical formula
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