why tarnished copper vessels are cleaned with lime juice or tamarind
Copper vessel gets tarnished due to copper oxide layer formed on its surface.Copper oxide is basic in nature.Lemon or tamarind is acidic.Hence, when we rub tarnished copper vessel with lemon juice or tamarind, the basic copper oxider reacts with acid(citric acid) present in the lemon or tamarind to form a salt which is washed away with water.Hence,the vessel gets cleaned.
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copper oxide layer formed on its surface.Copper oxide is basic in nature.Lemon or tamarind is acidic.Hence, when we rub tarnished copper vessel with lemon juice or tamarind, the basic copper oxider reacts with acid(citric acid) present in the lemon or tamarind to form a salt which is washed away with water.Hence,the vessel gets cleaned.
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Copper oxide layer takes place on the surface of copper vessel and CuO is basic in nature and tamarind/lime juice is acidic in nature so when we clean copper vessel with tamarind juice neutralisation reaction takes place therefore, salt and water is formed. The water formed removes the salt and hence copper vessel is cleaned..
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Copper is tarnished i.e., it undergoes corrosion in presence of air.
Copper + Carbon dioxide + Water + Oxygen -> Copper Carbonate + Copper hydroxide
The nature of its corrosive substance is basic (basic copper carbonate). Thus substances of acidic behaviour are generally used to neutralize the basic nature and dissolve the corrosive layer of basic copper carbonate. This evinces a clean and shiny brown layer (original) of copper.
Copper + Carbon dioxide + Water + Oxygen -> Copper Carbonate + Copper hydroxide
The nature of its corrosive substance is basic (basic copper carbonate). Thus substances of acidic behaviour are generally used to neutralize the basic nature and dissolve the corrosive layer of basic copper carbonate. This evinces a clean and shiny brown layer (original) of copper.
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The tarnished copper vessels have a layer of oxide of copper due to which it appears green.. Lime juice or tamarind has acid citric and tartaric acid respectively which on rubbing with oxide of copper neutralize its basic nature and hence the neutral salt is formed and the greenish layer is removed (metallic oxides r basic in nature)
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Copper reacts with moist carbon dioxide in air to form copper carbonate and as a result, copper vessel loses its shiny brown surface forming a green layer of copper carbonate.?The citric acid present in the lemon or tamarind neutralises the basis copper carbonate and dissolves the layer.
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