Why the colour of potassium permanganate disappears if it is added to warm solution of ethanol?
When potassium permanganate reacts with ethanol, it releases nascent oxygen. ie, an atom of oxygen thus converting the ethanol to acetic acid. Initially colour disappears because coloured permanganate ions of potassium permanganate are consumed to oxidise ethanol.
C2H5OH (WITH ALKALINE KMnO4) CH3COOH+H2O
2)When excess is added colour does not change because there is no more alcohol left and hence there is no reaction