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Page No 19:

Question 1:

Which of the following correctly represents 360g of water?
(i) 2 moles of H2O
(ii) 20 moles of water
(iii) 6.022 × 1023 molecules of water
(iv) 1.2044 ×1025molecules of water
(a) (i)
(b) (i) and (iv)
(c) (ii) and (iii)
(d) (ii) and (iv)

Answer:

(i) 2 moles of water = 18×2 = 36 grams of water(ii) 20 moles of water = 18×20 = 360 grams of water(iii) 6.022×1023 molecules of water = 1 mole of water = 18 grams of water(iv) 1.2044 × 1025 molecules of water = 1.2044×10256.022×1023=20 moles of water = 360 grams of water
Hence, the correct answer is option d.

Page No 19:

Question 2:

Which of the following statements is not true about an atom?
(a) Atoms are not able to exist independently
(b) Atoms are the basic units from which molecules and ions are formed
(c) Atoms are always neutral in nature
(d) Atoms aggregate in large numbers to form the matter that we can see, feel or touch

Answer:

Atoms of inert gases like neon and argon exist independently.
Hence, the correct answer is option a.

Page No 19:

Question 3:

The chemical symbol for nitrogen gas is
(a) Ni
(b) N2
(c) N+
(d) N

Answer:

Nitrogen exists as a diatomic molecule and the symbol is N2.
Hence, the correct answer is option b.

Page No 19:

Question 4:

The chemical symbol for sodium is
(a) So
(b) Sd
(c) NA
(d) Na

Answer:

The symbol for sodium is Na.
Hence, the correct answer is option d.
 

Page No 19:

Question 5:

Which of the following would weigh the highest?
(a) 0.2 mole of sucrose (C12 H22 O11)
(b) 2 moles of CO2
(c) 2 moles of CaCO3
(d) 10 moles of H2O

Answer:

Mass=number of moles×molar mass
(a) 0.2 moles of sucrose = 0.2 ×342.3 grams=68.46 grams (b) 2 moles of CO2 = 2×44= 88 grams(c) 2 moles of CaCO3= 2×100 = 200 grams(d) 10 moles of H2O = 10×18 =180 grams 
Hence, the correct answer is option c.

Page No 19:

Question 6:

Which of the following has maximum number of atoms?
(a) 18g of H2O
(b) 18g of O2
(c) 18g of CO2
(d) 18g of CH4

Answer:

Number of atoms = mass of the substance ×Number of atoms in a molecule × NaMolar Mass(a) 18 grams of Water = 1 mole = 6.022 ×1023 molecules = 3×6.022 ×1023 = 1.8066×1024 atoms(b) 18 grams of Oxygen = 18×2 32×6.022 ×1023 =6.77×1023 atoms(c) 18 grams of CO2 =18×344×6.022 ×1023= 7.39 ×1023 atoms(d) 18 grams of CH4 = 18×516×6.022 ×1023=3.38 ×1024 atoms
Hence, the correct answer is option d.
 

Page No 19:

Question 7:

Which of the following contains maximum number of molecules?
(a) 1g CO2
(b) 1g N2
(c) 1g H2
(d) 1g CH4

Answer:

(a) 1 gram of CO2 = 144×6.022 ×1023 = 1.368 ×1023 molecules(b) 1 gram of N2= 128×6.022 ×1023= 2.15×1022 molecules(c) 1 gram of H2 = 12×6.022 ×1023= 3.011×1023 molecules(d) 1 gram of CH4 = 116×6.022 ×1023= 3.76 ×1022 molecules
Hence, the correct answer is option c.



Page No 20:

Question 8:

Mass of one atom of oxygen is
(a) 166.023×1023g

(b) 326.023×1023g

(c) 16.023×1023g

(d) 8u

Answer:

Mass of one atom of Oxygen = Atomic mass6.022×1023= 166.022×1023
Hence, the correct answer is option a.

Page No 20:

Question 9:

3.42 g of sucrose are dissolved in 18 g of water in a beaker. The number of oxygen atoms in the solution are
(a) 6.68 × 1023
(b) 6.09 × 1022
(c) 6.022 × 1023
(d) 6.022 × 1021

Answer:

Moles of sucrose = 3.42342.3=0.01 mol1 mole of sucrose has 11×6.022×1023 oxygen atoms0.01 mole of sucrose will have 0.01×11×6.022×1023 = 0.11×6.022×1023 oxygen atomsNumber of moles of water = 1818= 1 mol1 mol of water has 1×6.022×1023 Oxygen atomsTotal oxygen atoms = 0.11×6.022×1023 + 1×6.022×1023 = 1.11×6.022×1023 = 6.68 11×1023 atoms
Hence, the correct answer is option a.

Page No 20:

Question 10:

A change in the physical state can be brought about
(a) only when energy is given to the system
(b) only when energy is taken out from the system
(c) when energy is either given to, or taken out from the system
(d) without any energy change

Answer:

A change in the physical state can be brought about when energy is either given to or taken out of the system. For example, during boiling of water heat energy is given out whereas in the case of melting of ice heat is taken by the system. The change in the state of matter occurs because of energy exchange between the system and the surroundings.

Page No 20:

Question 11:

Which of the following represents a correct chemical formula? Name it.
(a) CaCl
(b) BiPO4
(c) NaSO4
(d) NaS

Answer:

(a) Valency of Ca is 2 and Cl is 1. The correct formula is CaCl2.
(b) Valency of Bi is 3 and PO4 is 3. The correct formula is BiPO4.
(c) Valency of Na is 1 and SO4 is 2. The correct formula is Na2SO4.
(d) Valency of Na is 1 and S is 2. The correct formula is Na2S.
Hence, the correct answer is option b.
 

Page No 20:

Question 12:

Write the molecular formulae for the following compounds
(a) Copper (II) bromide
(b) Aluminium (III) nitrate
(c) Calcium (II) phosphate
(d) Iron (III) sulphide
(e) Mercury (II) chloride
(f) Magnesium (II) acetate

Answer:

(a) CuBr2
(b) Al(NO3)3
(c) Ca3(PO4)2
(d) Fe2S3
(e) HgCl2
(f) Mg(CH3COO)2
 

Page No 20:

Question 13:

Write the molecular formulae of all the compounds that can be formed by the combination of following ions
Cu2+, Na+, Fe3+, Cl-, SO42-, PO43-

Answer:

Cations: Cu2+,  Na+, Fe3+
Anions: Cl-, SO42-, PO43-

CuCl2, CuSO4, Cu3(PO4)2
NaCl, Na2SO4, Na3PO4
FeCl3, Fe2(SO4)3, FePO4

Page No 20:

Question 14:

Write the cations and anions present (if any) in the following compounds
(a) CH3COONa
(b) NaCl
(c) H2
(d) NH4NO3

Answer:

(a) CH3COO- and Na+
(b) Na+ and Cl-
(c) No ions are present in H2
(d) NH4+ and NO3-



Page No 21:

Question 15:

Give the formulae of the compounds formed from the following sets of elements
(a) Calcium and fluorine
(b) Hydrogen and sulphur
(c) Nitrogen and hydrogen
(d) Carbon and chlorine
(e) Sodium and oxygen
(f) Carbon and oxygen

Answer:

(a) CaF2
(b) H2S
(c) NH3
(d) CCl4
(e) Na2O
(f) CO
(g) CO2

Page No 21:

Question 16:

Which of the following symbols of elements are incorrect? Give their correct symbols

(a) Cobalt CO
(b) Carbon c
(c) Aluminium AL
(d) Helium He
(e) Sodium So

Answer:

(a) Cobalt Co
(b) Carbon C
(c) Aluminium Al
(d) Helium He
(e) Sodium Na

Page No 21:

Question 17:

Give the chemical formulae for the following compounds and compute the ratio by mass of the combining elements in each one of them. (You may use appendix-III).
(a) Ammonia
(b) Carbon monoxide
(c) Hydrogen chloride
(d) Aluminium fluoride
(e) Magnesium sulphide

Answer:

Chemical Formula Ratio by mass of combining atoms
Ammonia (NH3) N(1): H(3) [14:3]
Carbon monoxide (CO) C(1): O(1) [3:4]
Hydrogen chloride (HCl) H(1): Cl(1) [1:35.5] or [2:71]
Aluminium fluoride (AlF3) Al(1): F(3) [9:19]
Magnesium sulphide (MgS) Mg(1): S(1) [3:4] 

Page No 21:

Question 18:

State the number of atoms present in each of the following chemical species

(a) CO32-

(b) PO43-

(c) P2O5

(d) CO

Answer:

 a CO32- = 1 atom of C+3 atoms of O=4 atomsb PO43- = 1 atom of P +4 atoms of O=5 atoms(c) P2O5 = 2 atoms of P + 5 atoms of O=7 atoms(d) CO = 1 atom of C+ 1 atom of O=2 atoms
 

Page No 21:

Question 19:

What is the fraction of the mass of water due to neutrons?

Answer:

Mass of one mole(NA)of neutrons = 1 gramMass of 1 neutron = 1NA gramsMass of 1 mole of H2O = 18 gramsMass of one molecule of water = 18NA gramsNumber of neutrons in one atom of H = 0Number of neutrons in one atom of O = 8Mass of 8 neutrons (in H2O) = 8NAFraction of mass of water due to neutrons =8NA/18NA = 818=49

Page No 21:

Question 20:

Does the solubility of a substance change with temperature? Explain with the help of an example.

Answer:

Yes, the solubility of a substance changes with temperature. It generally increases with temperature. For example, more sugar can be dissolved in hot water as compared to cold water.

Page No 21:

Question 21:

Classify each of the following on the basis of their atomicity.
 

(a) F2 (b) NO2 (c) N2O (d) C2H6 (e) P4 (f) H2O2
(g) P4O10 (H) O3 (i) HCl (j) CH4 (k) He (l) Ag

Answer:

Monoatomic: He, Ag
Diatomic: F2, HCl
Polyatomic with atomicity > 2
Atomicity (3) = NO2, N2O, O3
Atomicity (4) = P4, H2O2
Atomicity (5) = CH4
Atomicity (8) = C2H6
Atomicity (14) = P4O10
 

Page No 21:

Question 22:

You are provided with a fine white coloured powder which is either sugar or salt. How would you identify it without tasting?

Answer:

Salt and sugar can be differentiated from each other, by heating or dissolving in water.
(i) Sugar powder is charred to black on heating, whereas salt do not change.
(ii) A salt solution conducts electricity due to the formation of ions in the solution, whereas a sugar solution does not do so.
 

Page No 21:

Question 23:

Calculate the number of moles of magnesium present in a magnesium ribbon weighing 12 g. Molar atomic mass of magnesium is 24g mol–1.

Answer:

The atomic mass of Mg = 24 g/mol
24 grams of Magnesium = 1 mol
Number of moles in 12g of Mg =Given massMolar mass=1224=0.5 mol



Page No 22:

Question 24:

Verify by calculating that
(a) 5 moles of CO2and 5 moles of H2O do not have the same mass.
(b) 240 g of calcium and 240 g magnesium elements have a mole ratio of 3:5.

Answer:

(a) Mass of 1 mole of CO2 = 44 gramsMass of 5 moles of CO2 = 44×5 = 220 gramsMass of 1 mole of H2O = 18 gramsMass of 5 moles of H2O = 18×5 = 90 grams(b) Molar mass of Ca = 40 grams = 1 moleNumber of  moles in 240 grams of Ca = 24040=6Molar mass of Mg = 24 grams = 1 moleNumber of moles in 240 grams of Mg =24024=10Mole ratio of Ca and Mg = 6:10 = 3:5

Page No 22:

Question 25:

Find the ratio by mass of the combining elements in the following compounds. (You may use Appendix-III)
 

(a) CaCO3 (d) C2H5OH
(b) MgCl2 (e) NH3
(c) H2SO4 (f) Ca(OH)2

Answer:

(a) Ca : C : O = 40 : 12 : 16×3 = 40 : 12 : 48 = 10 : 3 :12(b) Mg: Cl = 24 : 35.5×2 = 24: 71(c) H:S:O = 1×2: 32: 4×16 = 2:32: 64 = 1:16: 32(d) C:H:O = 12:1×6:16 = 12:6:16 = 6:3:8(e) N:H = 14:3(f) Ca:O:H = 40 : 32: 2 = 20:16:1

Page No 22:

Question 26:

Calcium chloride when dissolved in water dissociates into its ions according to the following equation.
CaCl2(aq) → Ca2+ (aq) + 2Cl(aq)
Calculate the number of ions obtained from CaCl2when 222 g of it is dissolved in water.

Answer:

CaCl2 (aq) → Ca2+ (aq) + 2Cl– (aq)
111 grams (1 mole) 1 mole + 2 moles222 grams (2 moles) 2 moles + 4 molesTotal number of ions given by 2 moles of CaCl2 =6Number of ions = Number of moles of ions × NA = 6 ×6.022×1023 = 3.6132 ×1024 ions

Page No 22:

Question 27:

The difference in the mass of 100 moles each of sodium atoms and sodium ions is 5.48002 g. Compute the mass of an electron.

Answer:

Number of electrons in Na atom = 11 
Number of electrons in Na+ = 10
The difference of the number of electrons for 1 mole of Na atom and Na+ = 1 mole
For 100 moles the difference will be 100 moles of electrons
Mass of 100 moles of electrons= 5.48002 g
Mass of 1 mole of electron =5.48002100gMass of one electron = 5.48002100×6.022×1023 = 9.1 ×10-28 g = 9.1 ×10-31 kg

Page No 22:

Question 28:

Cinnabar (HgS) is a prominent ore of mercury. How many grams of mercury are present in 225 g of pure HgS? Molar mass of Hg and S are 200.6 g mol–1 and 32 g mol–1 respectively.

Answer:

The molar mass of HgS = 200.6 + 32 = 232.6 grams
Mass of Hg in 232.6 of HgS = 200.6 grams
Mass of Hg in 225 grams of HgS =200.6232.6×225 = 194.04 grams
 

Page No 22:

Question 29:

The mass of one steel screw is 4.11g. Find the mass of one mole of these steel screws. Compare this value with the mass of the Earth (5.98 × 1024kg). Which one of the two is heavier and by how many times?

Answer:

Mass of 1 screws = 4.11 grams
Mass of 1 mole of screws = 4.11 ×6.022×1023 = 2.475 ×1024 grams = 2.475 ×1021 kgMass of earthMass of 1 mole screws= 5.98 ×1024 kg2.475 ×1021 kg = 2416 It shows that earth is 2416 times heavier than one mole of screws.

Page No 22:

Question 30:

A sample of vitamic C is known to contain 2.58 ×1024 oxygen atoms. How many moles of oxygen atoms are present in the sample?

Answer:

Number of oxygen atoms in the sample = 2.58 ×10246.022×1023 atoms of oxygen = 1 mole2.58 ×1024 atoms of oxygen =2.58×10246.022 ×1023moles = 4.28 moles

Page No 22:

Question 31:

Raunak took 5 moles of carbon atoms in a container and Krish also took 5 moles of sodium atoms in another container of same weight. (a) Whose container is heavier? (b) Whose container has more number of atoms?

Answer:

(a) Mass of container containing 5 moles of C atoms = 5×12 = 60 gMass of container containing 5 moles of Na atoms = 5 × 23 = 115 gHence, container of krish is heavier.(b) Both containers have same number of atoms since they contain same number of moles.

Page No 22:

Question 32:

Fill in the missing data in the Table 3.1

Table 3.1

Species H2O CO2 Na atom MgCl2
Property        
No. of moles 2 0.5
No. of particles 3.011×1023
Mass 36g 115 g

Answer:

 

Species H2O CO2 Na atom MgCl2
Property        
No. of moles 2 0.5 5 0.5
No. of particles 1.2044× 1024 3.011×1023 5×6.022×1023 = 3.011×1023 0.5×6.022×1023×3 = 9.033×1023
Mass 36 grams 22 grams 115 grams  47.5 grams

Page No 22:

Question 33:

The visible universe is estimated to contain 1022 stars. How many moles of stars are present in the visible universe?

Answer:

1 Mole of stars = 6.022 × 1023 starsNumber of moles of stars = 10226.023 × 1023                                              = 0.0166 moles



Page No 23:

Question 34:

What is the SI prefix for each of the following multiples and submultiples of a unit?
(a) 103
(b) 10–1
(c) 10–2
(d) 10–6
(e) 10–9
(f) 10–12

Answer:

(a) 103 = kilo(b) 10-1 = deci(c) 10-2 = centi(d) 10-6 = micro(e) 10-9 = nano(f) 10-12 = pico

Page No 23:

Question 35:

Express each of the following in kilograms
(a) 5.84 × 10–3 mg
(b) 58.34 g
(c) 0.584 g
(d) 5.873 × 10–21 g

Answer:

(a) 5.84 × 10-3mg   = 5.84 × 10-3103×103kg = 5.84 × 10-9 kg(b) 58.34 g   = 58.34103 = 5.834 × 10-2 kg(c) 0.584 g   =0.584103 kg = 5.84 × 10-4 kg(d) 5.873 × 10-21 g   = 5.873 × 10-21103 = 5.873 × 10-24 kg

Page No 23:

Question 36:

Compute the difference in masses of 103 moles each of magnesium atoms and magnesium ions.
(Mass of an electron = 9.1 × 10–31 kg)

Answer:

Mg2+ion = 10 electronsMg atom = 12 electronsDifference between Mg2+ and Mg = 2 moles of electronsThe difference between 103 moles of Mg and 103 moles of Mg2+ = 103 × 2 moles of electronsMass 0f 103 × 2 moles of eletrons = 2 × 103 × 6.022 × 1023 × 9.1 × 10-31 kg = 1.096 × 10-3 kg

Page No 23:

Question 37:

Which has more number of atoms?
100g of N2 or 100 g of NH3

Answer:

(i) 100 grams of N2 = 10028 molesNumber of molecules = 10028×6.022 ×1023 moleculesNumber of atoms = 2×10028×6.022 ×1023 atoms = 43.01 ×1023  atoms(ii) 100 grams of NH3 = 10017 molesNumber of molecules = 10017×6.022 ×1023 moleculesNumber of atoms = 10017×6.022×1023×4 atoms = 141.69 ×1023 atomsThus,NH3 would have more atoms.

Page No 23:

Question 38:

Compute the number of ions present in 5.85 g of sodium chloride.

Answer:

1 mole of NaCl = 23 + 35.5 = 58.5 grams of NaCl Number of moles in 5085 grams of NaCl =508558.5 = 0.1 moles Each NaCl formula unit = Na+ + Cl- = 2 ions Number of ions = 0.2× 6.022×1023 = 1.2044×1023 ions
 

Page No 23:

Question 39:

A gold sample contains 90% of gold and the rest copper. How many atoms of gold are present in one gram of this sample of gold?

Answer:

1 g of gold sample contains = 90100 = 0.9 g goldNumber of moles of gold = Mass of goldAtomic mass of gold = 0.9197 = 0.00461 mole of gold contains = 6.022 × 1023 atoms0.0046 mole of gold = 6.022 × 1023 × 0.0046 = 2.77 × 1021 atoms

Page No 23:

Question 40:

What are ionic and molecular compounds? Give examples.

Answer:

An ionic compound is a compound formed due to the transfer of electrons between the reacting species.  An ionic compound contains a cation which is a positive ion and an anion which is a negative ion. For example, sodium chloride is an ionic compound made up of  Na+ and Cl- ions. On the other hand, a molecular compound is a compound that is formed by sharing of electrons. It mainly consists of molecules. For example, ammonia (NH3), carbon dioxide (CO2).

Page No 23:

Question 41:

Compute the difference in masses of one mole each of aluminium atoms and one mole of its ions. (Mass of an electron is 9.1 × 10–28 g). Which one is heavier?

Answer:

Mass of Aluminium = 27 g mol-1AlAl3++3e-  (3 moles of electrons)Mass of 3 moles of electrons = 3 ×(9.1 × 10-28) × 6.022 × 1023 g = 0.00164 gMolar mass of Al3+ = 27 - 0.00164 g mol-1 = 26.9984 g mol-1Difference = 27 - 0.00164 g mol-1 = 26.9984 g mol-1

Page No 23:

Question 42:

A silver ornament of mass ‘m’ gram is polished with gold equivalent to 1% of the mass of silver. Compute the ratio of the number of atoms of gold and silver in the ornament.

Answer:

Mass of gold = m100 gramsNumber of atoms of silver = MassAtomic mass×NA = m108×NANumber of atoms of gold = m100×197×NARatio of number of atoms of gold to silver = Au:Ag = m100×197×NA : m108×NA                                                                                          =108:100×197                                                                                           = 108: 19700                                                                                          = 1:182.41

Page No 23:

Question 43:

A sample of ethane (C2H6) gas has the same mass as 1.5 ×1020 molecules of methane (CH4). How many C2H6 molecules does the sample of gas contain?

Answer:

Molar mass of CH4 = 16 grams = 6.022×1023 moleculesThus, 6.022 ×1023 molecules of CH4 will have mass = 16 gramsTherefore, 1.5×1020 molecules of CH4 will have mass = 166.022×1023×1.5×1020 =4×10-3  gramsMolar mass of C2H6 = 30 g/mol = 6.022 ×1023 moleculesThus, 30 grams of C2H6 have molecules = 6.022×1023 Therefore, 4×10-3 grams of C2H6 will have molecules =6.022×102330×4×10-3 = 0.803 ×1020 = 8.03 ×1019

Page No 23:

Question 44:

Fill in the blanks
(a) In a chemical reaction, the sum of the masses of the reactants and products remains unchanged. This is called ————.
(b) A group of atoms carrying a fixed charge on them is called ————.
(c) The formula unit mass of Ca3 (PO4)2is ————.
(d) Formula of sodium carbonate is ———— and that of ammonium sulphate is ————.

Answer:

(a) Law of conservation of mass
(b) Polyatomic ion
c3×40 + 2×31 + 8×16 = 120 + 62 + 128 = 310 u
(d) Na2CO3, (NH4)2SO4



Page No 24:

Question 45:

Complete the following crossword puzzle Figure by using the name of the chemical elements. Use the data given in Table 3.2.

Table 3.2

Across Down
2. The element used by Rutherford during his α–scattering experiment 1. A white lustrous metal used for making ornaments and which tends to get tarnished black in the presence of moist air
3. An element which forms rust on exposure to moist air 4. Both brass and bronze are alloys of the element
5. A very reactive non-metal stored under water 6. The metal which exists in the liquid state at room temperature
7. Zinc metal when treated with dilute hydrochloric acid produces a gas of this element which when tested with burning splinter produces a pop sound. 8. An element with symbol Pb
 

Answer:

1. Silver
2. Gold
3. Iron
4. Copper
5. Phosphorous
6. Mercury
7. Hydrogen
8. Lead

Page No 24:

Question 46:

In this crossword puzzle Figure, names of 11 elements are hidden. Symbols of these are given below. Complete the puzzle.
 

1. Cl 7. He
2. H 8. F
3. Ar 9. Kr
4. O 10. Rn
5. Xe 11. Ne
6. N    



(b) Identify the total number of inert gases, their names and symbols from this cross word puzzle.

Answer:

ure(a) 1. Chlorine

2. Hydrogen
3. Argon
4. Oxygen
5. Xenon
6. Nitrogen
7. Helium
8. Fluorine
9. Krypton
10.Radon
11. Neon

(b) Argon, Xenon, Helium, Krypton and Neon are noble gases.



Page No 25:

Question 47:

Write the formulae for the following and calculate the molecular mass for each one of them.
(a) Caustic potash
(b) Baking powder
(c) Lime stone
(d) Caustic soda
(e) Ethanol
(f) Common salt

Answer:

(a) Caustic Potash, KOH = (39+16+1) = 56 g/mol
(b) Baking powder, NaHCO3 = (23 +1+12+48)= 84 g/mol 
(c) Limestone, CaCO3 = (40+12+48) =100 g/mol
(d) Caustic soda, NaOH = (23+16+1) = 40 g/mol
(e) Ethanol, C2H5OH = (24 + 6 + 16) = 46 g/mol
(f) Common salt, NaCl = (23 + 35.5) = 58.5 g/mol

Page No 25:

Question 48:

In photosynthesis, 6 molecules of carbon dioxide combine with an equal number of water molecules through a complex series of reactions to give a molecule of glucose having a molecular formula C6H12O6. How many grams of water would be required to produce 18 g of glucose? Compute the volume of water so consumed assuming the density of water to be 1 g cm–3.

Answer:

6CO2 + 6H2O SunlightChlorophyll C6H12O6 + 6O21 mole(180 grams) of glucose needs 6 moles (6×18 grams) of H2O1 gram of glucose will need 108180 of H2O18 grams of glucose will need 108180×18 = 10.8 gramsVolume of water used = MassDensity =10.81= 10.8 cm3



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