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different types of isomerism

_{p}) are related as ${\mathrm{K}}_{\mathrm{p}}=\frac{4{\mathrm{\alpha}}^{2}\mathrm{P}}{\left(1-{\mathrm{\alpha}}^{2}\right)}$?(1) ${\mathrm{N}}_{2}{\mathrm{O}}_{4}\left(\mathrm{g}\right)\rightleftharpoons 2{\mathrm{NO}}_{2}\left(\mathrm{g}\right)$

(2) ${\mathrm{H}}_{2}\left(\mathrm{g}\right)+{\mathrm{I}}_{2}\left(\mathrm{g}\right)\rightleftharpoons 2\mathrm{HI}\left(\mathrm{g}\right)$

(3) ${\mathrm{N}}_{2}\left(\mathrm{g}\right)+3{\mathrm{H}}_{2}\left(\mathrm{g}\right)\rightleftharpoons 2{\mathrm{NH}}_{3}\left(\mathrm{g}\right)$

(4) ${\mathrm{PCl}}_{3}\left(\mathrm{g}\right)+{\mathrm{Cl}}_{2}\left(\mathrm{g}\right)\rightleftharpoons {\mathrm{PCl}}_{5}\left(\mathrm{g}\right)$

What is the bond order of N

_{2}+?^{o}C. If the work done in this process is 3KJ,then find the final temperature of the gas (C_{v}=20J/mol)