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Syllabus
(1) 0.003 kg hr–1
(2) 0.007 kg hr–1
(3) 0.006 kg hr–1
(4) 0.00017 kg hr–1
22. In dilute aqueous H2SO4, the complex diaquoudioxalatoferrate (II) is oxidized by MnO4-. For this reaction, the ratio of the rate of change of [H+] to the rate of change of [MnO4-] is
Wooden article and freshly cut tree show activity of 7.6 and and 15.2 min-1 gm-1 of carbon (t1/2= 5760 years) respectively. The age of article in years, is
A(s) H2O------ 2B(s) + C(s)
If initially two moles of A is dissolved in 360g of H2O and left for decomposition at constant temperature (25 deg) Then PS in the given table is ( assuming A,B and C are miscible in water)
S.N. Time The vapour pressure of solution
1. 12 hr 20mm Hg
2 . 80hr PS
Vapour pressure of H2O at 25 deg is 24mm Hg(Log2 = 0.30)
a) e-k/x
b) x/k
c) k
d) ek/x
11. Statement -1: The half life of reaction with rate law, rate of reaction = is depend on initial concentration of reactant A at very high concentration.
Statement -2 : The reaction is first order at very low concentration of A.
(A) Statement -1 is true, statement-2 is true and Statement-2 is correct explanation for Statement-1.
(B) Statement -1 is true, Statement-2 true of Statement-2 is NOT correct explanation for Statement -1.
(C) Statement -1 is true, Statement-2 is false
(D) Statement -1 is false, Statement -2 is true.
Q12. For the reaction A B, the rate law expression is – = k [A]1/2. If initial concentration of A is [A]0, then
(A) The integerated rate expression is k =
(B) The graph of Vs t will be
(C) The half life period t1/2 =
(D) The time taken for 75% completion of reaction t3/4 =
57. The reaction , is supposed to follow the following mechanism.
Suggest the rate of law expression.
What is the value of of frequency factor?
C2H5 ---> C2H5 +HI is1.6*10 POWER -5 AT 600K AND 6.36 -10 POWER -3 AT 700K
CALCULATE THE ENERGY OF ACTIVATION FOR THIS REACTION