Prior to Rutherford, Eugene Goldstein had observed canal rays, which were composed of positively charged ions. After the discovery of the electron by J.J. Thomson, Goldstein suggested that since the atom is electrically neutral there must be a positively charged particle in the atom and tried to discover it. He used the "canal rays" observed to be moving against the electron flow in cathode ray tubes. After the electron had been removed from particles inside the cathode ray tube they became positively charged and moved towards the cathode. Most of the charged particles passed through the cathode, it being perforated, and produced a glow on the glass. At this point, Goldstein believed that he had discovered the proton.[2] When he calculated the ratio of charge to mass of this new particle (which in case of the electron was found to be the same for every gas that was used in the cathode ray tube) was found to be different when the gases used were changed. The reason was simple. What Goldstein assumed to be a proton was actually an ion. He gave up his work there. But promised that "he would return." However, he was widely ignored.
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