1= let p and q be 3 by 3 matrices p3= q3 and p2q= q2p , p not equal to q find determinant of p2+q2

2- no of 3 by 3 non sing matrices with 4 enteries as 1 and all other enteries is 0 is

P 3 = Q3  (1)
P2Q = Q2P (2)

Subtracting (2) from (1), we have
P3 -P2Q = Q3 -Q2P
P2( P-Q ) = Q2 (Q-P)
P2(P-Q) +Q2 (P-Q) = 0
(P2+Q2) (P-Q) = 0
As P is not equal to Q .
So (P2+Q2) = 0

2)In this case there is no particular method, you have to check for all the matrices for singularity .
So for the case of 4 ones and 5 zeros , we have 9! /(4!*5!) matrices possible.

Here are some of the matrices , which are non -singular .
Put the diagonal element as 1.111 , in this case there are six places  left , and we have to fill the by 5 zeros and one 1.Hence the number of arrangement is 6! /(5!) = 6111 , similar to above . it also has 6 cases.Some more cases are 001101010, in this matrix , just interchange the rows to get two more matrix .3 cases are there 110100001 , in this matrix , just interchange the rows to get two more matrix .3 cases are there 010110001 , three cases.010011100 , three cases.100010101 , three cases .So 12 + 15 = 27 casesThe key point here is do not put any row or column as zero . 

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