Balance the following chemical equations:

Dear Student

Oxidation is loss of electrons (electrons are added on right hand side of equation)
Reduction is gain of electrons (electrons are added on left hand side of the equation)

(i) First reaction is not an redox reaction. Hence cannot be balanced by ion electron method
    oxidation states of Mn, H or S is unchanged
(ii) oxidation: Cu(s) rightwards arrow for blank of Cu+(aq) + e
     reduction: Fe+3(aq) + e rightwards arrow for blank of Fe+2(aq)
     net reaction: Cu(s) + Fe+3(aq) rightwards arrow for blank of Cu+(aq) +  Fe+2(aq)
(iii) oxidation: Cu(s) rightwards arrow for blank of Cu+2(aq) + 2e
     reduction: [Ag+(aq) + e rightwards arrow for blank of Ag(s) ] x2    We have to multiply by 2 to cancel out electrons in oxidation half reaction
     net reaction: Cu(s) + 2Ag+(aq) rightwards arrow for blank of Cu+(aq) +  2Ag(s)
(iv) oxidation: Al(s) rightwards arrow for blank of Al+3(aq) + 3e] x2     We have to cross-multiply to cancel out electrons in both half reaction
     reduction: 2H+(aq) + 2e rightwards arrow for blank of H2(g) ] x3
     net reaction: 2Al(s) + 6H+(aq) rightwards arrow for blank of 2Al+3(aq) + 3H2(g)
(v) ​​​​​​​ oxidation: Ca(s) rightwards arrow for blank of Ca+2(aq) + 2e
     reduction: 2H+(aq) + 2e rightwards arrow for blank of H2(g) 
     net reaction: Ca(s) + 2H+(aq) rightwards arrow for blank of Ca+2(aq) + H2(g)
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Regards

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