Dear Experts,
I have calculated then energy released per atom in question 13 . It comes out to be 3.06eV . Answer given in the book is also d. However, I want to ask shouldn't there be electron gain enthalpy instead of electron affinity bcz electron affinity is not always equal to ega

Dear Experts, I have calculated then energy released per atom in question 13 . It comes out to be 3.06eV . Answer given in the book is also d. However, I want to ask shouldn't there be electron gain enthalpy instead of electron affinity bcz electron affinity is not always equal to ega 12.. The electronic configurations given below (A) 152, 2s2 2p6, 3s2 (C) 1s2, 2s2 2p6, 3s2 3p2 Which of these is expected ionisation enthalpy? for some neutral atoms are (B) 1s2, 2s2 2p6, 3sl (D) 1s2, 2s2 2p6, 3s2 3p3 to have the highest second I [Hint : B atom after losing outermost electron acquires noble gas configuration (stable configuration). It is difficult to remove the next electron from B + (Is2, 2s2 2p6) ion.] The amount of energy released when 10 atoms of iodine in vapour state are converted to I - ions is 4.9 x 10 13 J. What is the electron affinity of iodine in eV per atom? (a) 2.0 (c) 2.75 (b) 2.5 (d) 3.06 [Hint : Amount of energy released for 1 mole of iodine 13 x 6.02 x 1023 106 = 29.5 x 104 J = 295 kJ mol -1 I eV per atom = 96.3 kJ mop 1] Match the following lists and select the correct answer: List 1 (A) 1s2 2s22p6 3s2 3p6, 4s1 (B) 2s2 2p6, 3s2 3p6 (C) 1s2 2s2 2p6, 3s2 3p6 3d6, 4s2 (D) 1s2 2s2 2p5 2 c 3 (b) List 11 (1) d-block element (2) Halogen (3) Alkali metal (4) Noble gas D 4

Dear Student,

No, the book is correct in saying "to find electron affinity" because the definitions of both terms are as follows.

Electron affinity of an atom or molecule is the amount of energy released when an electron is added to a neutral atom or molecule to form a negative ion also, 

while,

Electron gain enthalphy is is the amount of energy released when an isolated gaseous atom accepts an electron to become a monovalent gaseous anion. 

so , you can say that Electron Affinity is just the same thing as Electron Gain Enthalpy but with only difference in the sign of energy.
electron affinity is positive generally.

electron affinity = - (electron gain enthalphy)

Hope this information will clear your doubts about topic.

If you have any more doubts just ask here on the forum and our experts will try to help you out as soon as possible.

Regards
 

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