Narayani Upadhyaya , asked a question
Subject: Chemistry , asked on 5/12/13

explain why cp is always greater than cv????

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Guru Prasad Singh , added an answer, on 8/12/13
393 helpful votes in Chemistry

The reason for Cp greater than Cv is very simple.

This can be easily demonstrated by First law of thermodynamics.

At constant Pressure


Where as,

At Constant Volume,


Since dV=0

Therefore dQ=dU     ---(2).

Therefore Cp=dU+P.dV

And Cv=dU

Therefore using the above relation Cp is greater than Cv.

Physical Meaning of why Cp is greater than Cv:

At constant volume, heat is required only to increase the internal energy of system while At constant Pressure heat is needed for increasing Internal energy as well as for doing the work to displace the piston of system through a distance. Therefore Cp has a greater value than Cv.

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Pavithra , added an answer, on 5/12/13
20 helpful votes in Chemistry

The air temperature reading is always taken in shade because due to the exposure of sunlight thermometer reading increases than the real temperature.

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Kamalbista , added an answer, on 5/12/12
2 unhelpful votes in Chemistry

explain why air temperature reading are always taken with thermometer in the shade?

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Angel Malik , added an answer, on 8/3/12
19 helpful votes in Chemistry

thanx dude.. a thumbs up frm mah side.. :)

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