For the reaction NH4Cl (s)          NH3 (g) + HCL (g) at 25 , enthalpy change DH = +177 kJ per mole and entropy change triangle DS = +285 JK-1mol-1.Calculate free energy change D G at 25°C and predict whether the reaction is spontaneous or not.

Dear student

    NH4Cl = NH + HCl

    dG = dH - TdS
For spontaneous reaction dG should be negative.

   dG = 177 X 103 J/mol - 298K X 285 J/K-mol
   dG = 92070 J/mol
  OR    92.07 kj/mol

​dG is positive so reaction is non spontaneous.

Regards

 

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