how to balance equation in partial method

Partial equation method- The steps involved in this method are:

  1. The given reaction is divided into two or more reactions which are called partial equations.
  2. Each partial equation is balanced by hit and trial method.
  3. The intermediate species are cancelled out by multiplying the partial equations by suitable numbers.
  4. Finally all partial equations are added to get the final balanced equation.

Example: Balance by partial method: NaOH + Cl2 → NaCl + NaClO3 +H2O

1) split the given equation into partial equations as follows:
i) NaOH + Cl2 → NaCl + NaClO + H2O
ii) NaOCl → NaCl + NaClO3

Balance the equations by hit and trial method:
i) 2NaOH + Cl2 → NaCl + NaClO + H2O
ii) 3NaOCl → 2NaCl + NaClO3

To cancel intermediate NaClO the partial balanced eqn i) is multiplied by 3 and the two equations are added to get the overall balanced equation.

(2 NaOH + Cl2→ NaCl + NaClO + H2O ) x 3
  3NaOCl → 2NaCl + NaClO3


The overall balanced equation:
6NaOH + 3 Cl2→5NaCl + NaClO3 + 3H2O

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