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Solution
Pressure due to dry air at 14C or 287 K = Pressure of gas at 14C − Vapour pressure of water at 14C
Pressure due to dry air at 14C or 287 K = 750 − 12 = 738 mm Hg
Volume of dry air at 14C or 287 K = 28 cm3
STP conditions imply Standard Temperature and Pressure, i.e., is 760 mm Hg and T is 273 K.
According to gas equation,
​​​​​​​P1V1T1=P2V2T2Putting all the given values, we get738×28287=760×V2273V2=25.9 cm3

Hence, the volume of dry air at STP is 25.9 cm3​​​​​​​.
 

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