Q.80. For 10 min each, at 27 ° C , from two identical holes nitrogen and an unknown gas are leaked into a common vessel of 31 capacity. The resulting pressure is 4.18 bar and the mixture contains 0.4 mole of nitrogen. The molar mass of the unknown gas is
(a) 112 g   m o l - 1
(b) 242 g   m o l - 1
(c) 224 g   m o l - 1
(D) 422 g   m o l - 1

Dear Student,

The computation are as expressed below,

n=PVRT=4.18×30.0821×300=0.5 molegiven moles of nitrogen = 0.4so moles of unknown gas = 0.5-0.4=0.1 moleby using grahm's law of diffusion we get,rN=no.of molestime taken=0.410=0.04 molminrunknown=0.110=0.01 molminwe know, rNrunknown =munknownmN0.040.01=munknown14.007munknown =224.112 gmolHence answer is Option (C) 224 gmol

Regards.

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