what is isothermal and isobaric change?

An isothermal process is a process in which temperature remains constant. This condition is written as ΔT = 0 i.e.  no change occurs in the temperature of the reaction system.

An isobaric process is a process in which pressure remains constant. This condition is written ΔP = 0 i.e. no change occurs in the pressure of the reaction system.

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An isothermal process is a change of a system, in which the temperature remains constant: ΔT = 0. This typically occurs when a system is in contact with an outside thermal reservoir (heat bath), and the change occurs slowly enough to allow the system to continually adjust to the temperature of the reservoir through heat exchange. In contrast, an adiabatic process is where a system exchanges no heat with its surroundings (Q = 0). In other words, in an isothermal process, the value ΔT = 0 but Q ≠ 0, while in an adiabatic process, ΔT ≠ 0 but Q = 0.

 

An isobaric process is a thermodynamic process in which the pressure stays constant. The term derives from the Greek isos, (equal), and barus, (heavy). The heat transferred to the system does work but also changes the internal energy of the system:

The yellow area represents the work done
 Q = Delta U + W,

According to the first law of thermodynamics, where W is work done by the system, U is internal energy, and Q is heat. Pressure-volume work by the closed system is defined as:

W = int ! p ,dV ,

where Δ means change over the whole process, whereas d denotes a differential. Since pressure is constant, this means that

 W = p Delta V, .

Applying the ideal gas law, this becomes

 W = n,R,Delta T

assuming that the quantity of gas stays constant, e.g., there is no phase transition during a chemical reaction. According to the equipartition theorem, the change in internal energy is related to the temperature of the system by

 Delta U = n,c_V,Delta T,

where c_V is specific heat at a constant volume.

Substituting the last two equations into the first equation produces:

 Q = n,c_V,Delta T + n,R,Delta T
 = n,(c_V + R),Delta T
 = n,c_P,Delta T ,

where c_P is specific heat at a constant pressure.

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