1. Why does lithium form covalent bond unlike other alkali which forms ionic

    bond? ​

Dear Student,

Lithium has  small size and has high charge density. Now, as per Fajan's rule, smaller the cation and higher the charge, greater will be the polarising power. As a result, Li has high polarising power. So, it polarises the anions which consequncy leads to the formation of covalent bond as greater the polarising power, greater will be covalent character.
Hence, Li forms covalent compounds. 

  • 2
Lithium is extremely small as compared to other alkali metals in size. So to remove electrons it requires lots of energy. Hence it forms covalent bond.
  • 5
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