Why the internal energy of a system cannot be determined?

Dear Student

Internal Energy of thesystem  is the sum of all energies present in the system. Which includes the energy of all atom ,their electrons  and components by their nuclei. ( Energy can be the  sum of translational KE + Rotational KE+ Potential energy + Vibrational energy etc ).
Now we can't determine everything all at the same time. So we calculate change in internal energy because in that case  U=Uf - Ui  and here we see that  it is the difference so here in case if some kind of  energy are constant then their difference will be neutralised.  And also the U  depends upon the initial and final point and not on the path followed from initial point to final point.


Regards

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The internal energy of a system has two components: K.E and P.E. K.E consist of various types of molecular motion and electronic movement of electrons, in the other hand, P.E is the sum of all the distribution: attractive interaction between nuclei and electrons, repulsive interaction between electrons, repulsive interaction between nuclei and interaction between molecule. Therefore, practically, it is not possible to measure the internal energy of a system from the contrubutions or K.E and P.E
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