Plz explain me sp3 and sp2 hybridisation? How do we come to know that a given compound issp3 or sp2hybridised?

Hybridisation

It states that atomic orbitals of slightly different energies combine to form a new set of equivalent orbitals (having the same energy and shape) known as hybrid orbitals.

These hybrid orbitals are more stable than atomic orbitals, and participate in bond formation.

  • sp2

    • Involves mixing of one s orbital and two p orbitals to give three sp2 orbitals

    • Hybrid orbitals have 33.33% s and 66.64% p character.

    • Three hybrid orbitals orient themselves in a trigonal planar fashion at an angle of 120°.

    • Example: B in BCl3 undergoes sp2 hybridisation.

  • sp3

    • Involves mixing of one s orbital and three p orbitals to give four sp3 orbitals

    • Hybrid orbitals have 25% s and 75% p character.

    • Four hybrid orbitals orient themselves in such a manner that each orbital is directed toward the four corners of a tetrahedron.

    • Example: C in CH4 undergoes sp3 hybridisation.

The number of sigma bonds around a central atom can give the information of type of hybridisation.

If total hybrid orbitals are 2, it is sp, 

If total hybrid orbitals are 3, it is sp2

If total hybrid orbitals are 4, it is sp3

 

  • 8

BY using formula of Hybridisation for organic compounds,

No. of hybridised orbital= no. of sigma bond(s)+no. of lone pair(s).

If its 3=>sp2 , 4=>sp3 .

For carbon in benzene,its= 3 sigma bonds + 0 lone pair=3{sp2}

  • -1

I AM GIVING U SHORT TRICK .IF A COMPOUND HAS 4 SIGMA BOND ,THREE SIGMA AND 1 LONE PAIR,2 SIGMA AND 2 LONE PAIR OR TREE LONE PAIR AND ONE SIGMA BOND THEN IT IS SP3 HYBRIDISED.NOW IF A COMPOUND HAS THREE SIGMA BOND ,2 SIGMA AND 1 LONE PAIR OR 2 LONE PAIR AND 1 SIGMA BOND THEN IT IS SP2 HYBRIDISED.JUST APPLY THIS TRICK AND U WILL GET THE REQUIRED ANSWER.I AM SURE THIS WILL HELP U.

  • 3
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