Calculate the heat of formation of benzene from the following data, assuming no resonance. Bondenergies :C  –  C = 83 kcal CC  = 140 kcalC  –  H = 99 kcal   Heat of atomisation of C = 170 .9 kcalHeat of atomisation of H = 52.1 kca1

The solution is as follows:

1. Heat of formation of C6H6 = 6 (C-C) + 6 (C-H ) + 3 (C=C) + 6 (atomisation of C) + 6 (atomisation of H)
 
                                = 2256.3 kcal

  • -100
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