Calculate the volume of gas liberated at anode at STP during the electrolysis of CuSO4 solution by passing current of 1 A for 16 minute and 5 second
  1. 56 ml
  2. 224 ml
  3. 112 ml
  4. 448 ml

Dear Student,

Anode : H2O  2H+ + 12O2 +2e-Cathode : Cu2+ + 2e-  CuQuantity of electricity passed, Q=Itor, Q=1×(16×60+5) = 1×965= 965 CAmount of electrons passed= 96596500=0.01 molOn passing 2 mol of e- ,12 mol of gas is evolved.So, on passing 0.01 mol of electrons, amount of gas evolved = 12×2×0.01=0.0025 mol Volume of O2 liberated = 0.0025×22.4=0.056 L=56 mlHence, the correct answer is (1)

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