. How is the concentration of a solute present in trace amount in a solution expressed?

Your friend is correct.

ppm or Parts per million  is a way of expressing the trace amount of solute in solution. Just as per cent means out of a hundred, so parts per million or ppm means out of a million. Usually describes the concentration of something in water or soil. 

Parts per million = ( Number of parts of the component / Total number of parts of all components of the solution ) × 106 
Suppose 1 mg of solute is present in 1 kg of solvent , it's concentration in ppm would be :
1 mg/1 kg x 106 
1 kg = 106 mg
So, 1 mg/ 106 mg x 106 = 1 ppm
       

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the concentration of trace amount solute is determined in terms of parts per million

Simply, you can learn it as-parts of solute per 1000000 parts of solvent

you can also remember it as solute in mg per kg of solvent

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