How would you account for the increasing oxidising power in series VO2 + < Cr2O7 2- < MnO4 - ?
The oxidation state of the transition metals in the given compounds is:
Ionic specie | VO2+ | Cr2O72- | MnO4- |
Oxidation state of metal | +5 | +6 | +7 |
The higher the magnitude of positive charge on the metal ion, greater is the oxidizing power of the metal, as the increasing order of oxidation state is +5 < +6 < +7, therefore the increasing order of the oxidizing power will be :
VO2+ < Cr2O72- < MnO4-.