Please solve question no 3:

Reactants $\stackrel{}{\to }$ products $∆\mathrm{G}$ = + 63 KJ mole^–1. This reaction is made to take place by coupling with
$$\begin{gathered} \left(1\right) \mathrm{ATP} \stackrel{{\mathrm{H}}_2\mathrm{O}}{\to } \mathrm{ADP} \\ \left(2\right) \mathrm{ATP} \stackrel{{\mathrm{H}}_2\mathrm{O}}{\to } \mathrm{A} \\ \left(3\right) \mathrm{ATP} \stackrel{{\mathrm{H}}_2\mathrm{O}}{\to } \mathrm{AMP} \\ \left(4\right) \mathrm{ADP} \stackrel{{\mathrm{H}}_2\mathrm{O}}{\to } \mathrm{A} \end{gathered}$$

Dear student ,

As per the given condition ,  reaction is non spontaneous ( as the value of its free energy is positive ) therefore in order to make it spontaneous this should be coupled with that reaction which  have large value of negative free energy , so in the given options ( 1) and (3) are correct 
Regards