[Pt(OH)2(NH3)4]SO4 and [PtSO(NH3)4](OH)2 HOW WILL YOU IDENTIFY THE ISOMERS WITH A CHEMICAL TEST
 

Please check the formula of your compounds.  They are probably, [Pt(OH)2(NH3)4](SO4)2 and [Pt(OH)2(NH3)4](SO4)2.
One distinguishes isomers by the chemical properties of the ionizable ions.
[Pt(OH)2(NH3)4](SO4)2 ionises in solution to give sulphate ions which give a white precipitate of barium sulphate on addition of barium chloride solution.while
 [Pt(SO4)2(NH3)4](OH)2 will ionise to give OH- ions which will turn phenolphthalein solution pink.

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