Solve this.:

23. The vapour pressure of pure benzene at 298 K is 97.0 mm Hg. The vapour pressure of solution containing 10.0 g of naphthalene (mol. wt. 128) in 100 g of benzene at 398 K will be.
A. 79.5 mm Hg.          B. 91.43 mm Hg
C. 81.45 mm Hg.        D. 66.5 mm Hg. 

 

Dear Student,
Please find the answer to your question
 
According to Rault’s law,
Po-­P/Po = w/m /w/m +W/M
Here, Po = 97 mm
p = ?
W = 10 g W = 100
M = ? M = 78
Substituting the various values in the above equation for Roult’slaw :
97 -p/97 = 10/m /2.175/m+39/78
1/16 = 2.175/2.175 + 0.5 m
m = 65.25
 
 
 

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