1st ques in not clearly visible
2. correct order option 4th because the correct order of decrease in +I effect is
-O- > CO- >COO- > C(CH3)3 > C(CH3)2CH > CH3 > CH2 > NH- >H
2. correct order option 4th because the correct order of decrease in +I effect is
-O- > CO- >COO- > C(CH3)3 > C(CH3)2CH > CH3 > CH2 > NH- >H